Expected and Unexpected Transformations of Manganese(III) Tris(4-nitrophenyl)corrole
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https://figshare.com/articles/dataset/Expected_and_Unexpected_Transformations_of_Manganese_III_Tris_4_nitrophenyl_corrole/2385472
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资源简介：
The
synthesis and characterization of manganese complexes of 5,10,15-tris(4-nitrophenyl)
corrole in different oxidation states are described. Adoption of established
protocols for the synthesis of (nitrido)manganese(V) complexes led
to the expected corrole derivative as a minor product, accompanied
by nitrogen atom insertion into the macrocycle. The major product
was fully characterized via the combination of spectroscopy and X-ray
crystallography as (nitrido)manganese(V) 6-azahemiporphycene.
创建时间：
2016-02-19
