Constitution of Grignard Reagent RMgCl in Tetrahydrofuran
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https://figshare.com/articles/dataset/Constitution_of_Grignard_Reagent_RMgCl_in_Tetrahydrofuran/3738225
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资源简介：
The constitution of Grignard reagent, RMgCl (R = Me, tBu, Ph or benzyl), was investigated in the solid state by means of X-ray crystallography
and in THF by coldspray ionization mass spectrometry (CSI-MS). Three types of crystal structures, (a) [Mg2(μ-Cl3)(THF)6]+·[RMgCl2(THF)]-, (b)
R2Mg4Cl6(THF)6, and (c) [2Mg2(μ-Cl3)(THF)6]+·[R4Mg2Cl2]2-, were identified, and MeMg2(μ-Cl3)(THF)4-6 were detected as major species of MeMgCl
in solution.
创建时间：
2016-08-20
