Exclusive Csp3–Csp3 vs Csp2–Csp3 Reductive Elimination from PtIV Governed by Ligand Constraints
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https://figshare.com/articles/dataset/Exclusive_Csp_sup_3_sup_Csp_sup_3_sup_vs_Csp_sup_2_sup_Csp_sup_3_sup_Reductive_Elimination_from_Pt_sup_IV_sup_Governed_by_Ligand_Constraints/2093998
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Selective reductive elimination of ethane (Csp3-Csp3 RE) was observed following bromide abstraction and subsequent thermolysis of a PtIV complex bearing both Csp3- and Csp2-hybridized hydrocarbyl ligands. Through a comparative experimental and theoretical study with two other PtIV complexes featuring greater conformational flexibility of the ligand scaffold, we show that the rigidity of a meridionally coordinating ligand raises the barrier for Csp2-Csp3 RE, resulting in unprecedented reactivity.
创建时间：
2016-02-12
