Rhodium-Catalyzed Regio‑, Diastereo‑, and Enantioselective Three-Component Carboamination of Dienes via C–H Activation
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https://figshare.com/articles/dataset/Rhodium-Catalyzed_Regio_Diastereo_and_Enantioselective_Three-Component_Carboamination_of_Dienes_via_C_H_Activation/14663605
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资源简介：
Reported herein is the rhodium-catalyzed
enantioselective three-component
coupling of arene, diene, and dioxazolone that occurs via C–H
activation en route to allyl intermediate. This carboamination reaction
affords chiral allylic amines in 1,2-selectivity, E-selectivity, and enantioselectivity, with electrophilic amination
of the π-allyl species being both regio- and enantio-determining.
创建时间：
2021-05-24
