Synthesis of (±)-Aphanorphine Using Rh-Catalyzed Cyclohydrocarbonylation
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https://figshare.com/articles/dataset/Synthesis_of_-Aphanorphine_Using_Rh-Catalyzed_Cyclohydrocarbonylation/5236231
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A facile formal synthesis to aphanorphine and its analogue is described, featuring Rh-catalyzed cyclohydrocarbonylation of 2-aminodihydronaphthalene to the bridged benzazepine core. Subsequent introduction of the methyl group and functional group transformation complete the synthesis of aphanorphine and its analogue over eight steps.
创建时间：
2017-07-24
