Blocking Intramolecular Cycloadditions between CC Triple Bonds and Electrophilic Phosphinidene Complexes: Generation of Intermediates Able To React with Arenes
收藏Figshare2016-10-18 更新2026-04-29 收录
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Electrophilic terminal phosphinidene complexes [R1P-W(CO)5] bearing 2-alkynylphenyl R1 substituents undergo a spontaneous cyclization to give intermediate five-membered species which are able to perform an electrophilic substitution reaction with toluene and mesitylene. An intramolecular version of this reaction is possible with appropriate R substituents on the CC triple bond.
创建时间：
2016-10-18
