Highly Enantioselective Ketone-Ene Reactions of Trifluoropyruvate: Significant Counterion Effect of the In(III)−PyBox Complex
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https://figshare.com/articles/dataset/Highly_Enantioselective_Ketone_Ene_Reactions_of_Trifluoropyruvate_Significant_Counterion_Effect_of_the_In_III_PyBox_Complex/2805892
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资源简介：
A chiral indium(III)−pybox complex catalyzed asymmetric ketone-ene reaction of trifluoropyruvate is described. Both aromatic and aliphatic 1,1-disubstituted alkenes reacted smoothly to give the enantioenriched tertiary homoallylic alcohols in good to excellent yields (up to 99%) and with excellent enantioselectivities (up to 98% ee).
创建时间：
2016-02-25
