A Two-Step, Stereoselective Synthesis of Nine- and Ten-Membered Carbocycles from Phthalates
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https://figshare.com/articles/dataset/A_Two_Step_Stereoselective_Synthesis_of_Nine_and_Ten_Membered_Carbocycles_from_Phthalates/2170822
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资源简介:
A two-step, stereoselective procedure
for the synthesis of nine-
and ten-membered carbocycles from readily available phthalates is
described. A variety of dialkyl phthalates have been transformed into
[6,n]-fused bicyclo systems (n =
5, 6, 7) by a dearomatization/cyclization process and then converted
into cyclonona- and cyclodecadienes through a bond cleavage reaction,
whereby both processes are promoted by alkaline metals in THF.
创建时间:
2016-02-13



