Formation of Chelated Counteranions Using Lewis Acidic Diboranes: Relevance to Isobutene Polymerization
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https://figshare.com/articles/dataset/Formation_of_Chelated_Counteranions_Using_Lewis_Acidic_Diboranes_Relevance_to_Isobutene_Polymerization/12074838
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The reactions of chelating diboranes with PhCMe2Cl and related initiators were studied by variable-temperature NMR spectroscopy. Although thermally stable ion-pairs featuring weakly coodinating anions
(WCA) are formed, isobutene polymerization is complicated by the tendency of these WCA to act as
hindered bases toward Brønsted acidic chain ends.
创建时间:
2007-11-05



