Mercury(II)-Mediated Cleavage of Cyclopropylcarbinols by an Intramolecular Sulfinyl Group as a Stereo- and Regioselective Route to Stereotriads and Stereotetrads
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Mercury_II_Mediated_Cleavage_of_Cyclopropylcarbinols_by_an_Intramolecular_Sulfinyl_Group_as_a_Stereo_and_Regioselective_Route_to_Stereotriads_and_Stereotetrads/2697157
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Mercury(II) salt mediated opening of cyclopropylcarbinols by an intramolecular sulfinyl group is disclosed. All four diastereomeric stereotriads have been prepared from cis- and trans-disubstituted cyclopropanes. The trisubstituted cyclopropanes also react regio- and stereoselectively to afford products possessing quaternary stereogenic centers. The reaction is clean and general.
创建时间：
2016-02-23
