Ru(II)-Catalyzed Tunable Cascade Reaction via C–H/C–C Bond Cleavage
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A facile synthesis of various 3-(alkoxyalkyl)-1H-indoles from pyrazolidinones, 2-acetylenic ketones, and alkyl alcohols via C–H/C–C bond activation has been developed. The reaction proceeds smoothly under the proper reaction conditions, and preliminary mechanistic studies suggest that NaOAc is crucial for C–C bond activation. The advantages of the present method represent a redox-neutral process and exhibit excellent chemo and regioselectivity.
创建时间：
2020-09-17
