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Palladium-Catalyzed Intermolecular Exchange between C–C and C–Si σ‑Bonds

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https://figshare.com/articles/dataset/Palladium-Catalyzed_Intermolecular_Exchange_between_C_C_and_C_Si_Bonds/5361031
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资源简介:
A palladium–isocyanide complex opens the two four-membered rings of benzocyclobutenone and silacyclobutane to merge them into an eight-membered ring skeleton. The present reaction provides a unique example of an intermolecular cross metathesis-type reaction between covalent σ-bonds of low polarity.
创建时间:
2017-08-31
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