Quasi-One-Step Six-Electron Electrochemical Reduction of an Octahedral Hexanuclear Molybdenum(II) Cluster
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Quasi-One-Step_Six-Electron_Electrochemical_Reduction_of_an_Octahedral_Hexanuclear_Molybdenum_II_Cluster/3970212
下载链接
链接失效反馈官方服务：
资源简介：
We report for the
first time quasi-one-step six-electron electrochemical reduction of
a new hexanuclear molybdenum(II) bromide cluster having terminal 3,5-dinitrobenzoate
ligands: [Mo6Br8(DNBA)6]2–. The electrochemical responses of the cluster were studied based
on cyclic (CV), differential pulse, and normal pulse voltammetries,
together with the analytical simulations of the CV and spectroelectrochemistry.
CV simulations have revealed that the electrochemical reaction of
the cluster proceeds in an EEEEEE scheme, and the potential differences
between the two adjacent reduction steps are in the range of 15–30
mV. These potential differences indicate quite smooth and quasi-one-step
six-electron reduction of the cluster.
创建时间：
2016-10-11
