Solid-state NMR data for: Sequential pore functionalization in MOFs for enhanced carbon dioxide capture

In \"Sequential Pore Functionalization in MOFs for Enhanced Carbon Dioxide Capture\", this dataset contains solid-state 13C NMR measurements of a copper (Cu(II))-based MOF, mCBMOF-1, including as-made, functionalized, and CO2-loaded samples. The NMR data provide molecular-level information on the sequential loading of NH3 followed by CO2 adsorption. In the associated study, the process was shown to generate a copper-carbamic acid complex within the MOF pores. These data support the study on sequential pore functionalization to enhance interactions with small molecules such as CO2.
, , , # Solid-state NMR data for: Sequential pore functionalization in MOFs for enhanced carbon dioxide capture

[https://doi.org/10.5061/dryad.v15dv426b](https://doi.org/10.5061/dryad.v15dv426b)

## Description of the data and file structure

This dataset includes solid-state 13C NMR data of as-made MOF and CO2 loading with functionalized MOF. The corresponding authors for the study '*Sequential Pore Functionalization in MOFs for Enhanced Carbon Dioxide Capture*', in which this dataset is utilized, are Dr. Hongliang Huang and Dr. Kyriakos C. Stylianou.

**Solid-state NMR** contains solid-state NMR data on 13C nuclei, which were collected at 400 MHz magnetic fields with magic angle spinning (MAS).

* The subfolder of “**as-made MOF**” represents materials without functionalization.
* The subfolder of \"**functionalized MOF**\" represents functionalization of as-made MOF.
* The subfolder of \"**CO2_functionalized MOF**\" represents functionalization of as-made MOF, followed by CO2 loading.
* The ...,