Dynamic Nuclear Polarization with a Water-Soluble Rigid Biradical
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https://figshare.com/articles/dataset/Dynamic_Nuclear_Polarization_with_a_Water_Soluble_Rigid_Biradical/2540566
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资源简介：
A new biradical polarizing agent, bTbtk-py, for dynamic
nuclear
polarization (DNP) experiments in aqueous media is reported. The synthesis
is discussed in light of the requirements of the optimum, theoretical,
biradical system. To date, the DNP NMR signal enhancement resulting
from bTbtk-py is the largest of any biradical in the ideal glycerol/water
solvent matrix, ε = 230. EPR and X-ray crystallography are used
to characterize the molecule and suggest approaches for further optimizing
the biradical distance and relative orientation.
创建时间：
2016-02-21
