Electroreductive Coupling of Optically Active α,β-Unsaturated Carbonyl Compounds with Diaryl Ketones: Asymmetric Synthesis of 4,5,5-Trisubstituted γ-Butyrolactones
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https://figshare.com/articles/dataset/Electroreductive_Coupling_of_Optically_Active_Unsaturated_Carbonyl_Compounds_with_Diaryl_Ketones_Asymmetric_Synthesis_of_4_5_5_Trisubstituted_Butyrolactones/2281222
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资源简介：
The electroreductive coupling of
optically active N-E-crotonoyl-
and N-cinnamoylimidazolidin-2-ones
and oxazolidin-2-ones with diaryl ketones in the presence of chlorotrimethylsilane
gave adducts with high diastereoselectivity. The adducts were readily
transformed to optically active 4,5,5-trisubstituted γ-butyrolactones
by treatment with TBAF.
创建时间：
2014-06-20
