Three-Dimensional Hybrid Framework Containing U2O13 Dimers Connected via Cation–Cation Interactions
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https://figshare.com/articles/dataset/Three_Dimensional_Hybrid_Framework_Containing_U_sub_2_sub_O_sub_13_sub_Dimers_Connected_via_Cation_Cation_Interactions/2617624
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A three-dimensional metal–organic framework with cation–cation interactions, UO2(NO2TA)2(H2O) (1), was synthesized hydrothermally and characterized via single-crystal X-ray diffraction, powder X-ray diffraction, UV–vis spectroscopy, and fluorescence spectroscopy (NO2TA = 2-nitroterephthalic acid). 1 crystallizes in the monoclinic space group P21/n [a = 11.6970(7) Å, b = 15.1449(9) Å, c = 12.2564(8) Å, and β = 109.193(1)°] and contains U2O13 dimers. The UV–vis spectrum of 1 contains peaks attributable to both the ligand and the uranium cation. Furthermore, the ligand and the uranium cation of 1 can be independently excited, giving rise to two different luminescent spectra.
创建时间：
2016-02-23
