Synthesis of Nitrogen-Bridged Terthiophenes by Tandem Buchwald–Hartwig Coupling and Their Properties
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The first synthesis of nitrogen-bridged terthiophenes (NBTTs) has been achieved by a tandem Buchwald–Hartwig coupling of 3,3′,3″,4′-tetrabromo-2,2′:5′,2″-terthiophene. Several NBTT derivatives bearing aryl or alkyl moieties on the N-atoms could be synthesized. Their fundamental electrochemical characteristics and HOMO–LUMO levels were found to be influenced by the substituents on the N-atoms.
创建时间：
2016-02-20
