Rhodium Complexes Bearing PAlP Pincer Ligands
收藏NIAID Data Ecosystem2026-03-10 收录
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We report rhodium complexes bearing PAlP pincer ligands with an X-type aluminyl moiety. IR spectroscopy and single-crystal X-ray diffraction analysis of a carbonyl complex exhibit the considerable σ-donating ability of the aluminyl ligand, whose Lewis acidity is confirmed through coordination of pyridine to the aluminum center. The X-type PAlP–Rh complexes catalyze C2-selective monoalkylation of pyridine with alkenes.
创建时间：
2018-06-04
