In Situ Hydrothermal Reduction of Neptunium(VI) as a Route to Neptunium(IV) Phosphonates
收藏NIAID Data Ecosystem2026-03-06 收录
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A lamellar neptunium(IV) methylphosphonate, Np(CH3PO3)(CH3PO3H)(NO3)(H2O)·H2O, has been prepared under hydrothermal conditions via the in situ reduction of NpVI to NpIV. The single crystal structure of this compound shows polar layers that are joined to one another via a hydrogen-bonding network involving interlayer water molecules. Magnetic susceptibility measurements demonstrate that the NpIV ions are magnetically isolated from one another.
创建时间:
2016-06-03



