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Synthesis of Enantiopure P‑Stereogenic Diphosphacrowns using P‑Stereogenic Secondary Phosphines

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_Enantiopure_P_Stereogenic_Diphosphacrowns_using_P_Stereogenic_Secondary_Phosphines/2433826
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A new synthetic route to enantiopure P-stereogenic benzodiphosphacrowns using a P-stereogenic secondary bisphosphine as the key building block is reported. Syntheses of the enantiomer and P-stereogenic crowns with various ring structures, as well as deboranation of the crown compounds and subsequent reaction with a platinum complex, are described.
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2016-02-19
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