Heptametallic Bowl-Shaped Complexes Derived from Conjugated Schiff-Base Macrocycles: Synthesis, Characterization, and X-ray Crystal Structures
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https://figshare.com/articles/dataset/Heptametallic_Bowl_Shaped_Complexes_Derived_from_Conjugated_Schiff_Base_Macrocycles_Synthesis_Characterization_and_X_ray_Crystal_Structures/3071695
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资源简介：
The reaction of chelating conjugated macrocycles 1a−c with
Zn(OAc)2 gives bowl-shaped heptanuclear Zn complexes featuring
Zn in tetrahedral, octahedral, and square-pyramidal geometries.
Crystallographic and NMR results indicate that vacant Zn coordination sites within the bowl may be accessed, suggesting that these
coordination complexes may be used as mimics for Zn fingers
and carbonic anhydrase.
创建时间：
2016-03-01
