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Two Azolium Rings Are Better Than One: A Strategy for Controlling Catenation and Morphology in Zn and Cu Metal–Organic Frameworks

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Two_Azolium_Rings_Are_Better_Than_One_A_Strategy_for_Controlling_Catenation_and_Morphology_in_Zn_and_Cu_Metal_Organic_Frameworks/2591539
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Four new azolium-containing metal–organic frameworks (MOFs) have been synthesized, where the azoliums are potential organocatalyst precursors. Modifying the number of azoliums on a standard biphenyl dicarboxylate strut affects the morphology or the degree of interpenetration in two representative types of MOFs: NbO-type Cu-paddlewheel 2D sheets and cubic IRMOFs.
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2016-02-22
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