Mechanistic Aspects of the Phosphine-Catalyzed Isomerization of Allenic Sulfones to 2‑Arylsulfonyl 1,3-Dienes
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https://figshare.com/articles/dataset/Mechanistic_Aspects_of_the_Phosphine_Catalyzed_Isomerization_of_Allenic_Sulfones_to_2_Arylsulfonyl_1_3_Dienes/2097250
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When an allenic sulfone is treated with a phosphine nucleophile and a proton shuttle, an isomerization to a 2-arylsulfonyl 1,3-diene occurs. Mechanistic aspects of the process were investigated leading to the formulation of a mechanism for the reaction. Some further optimization studies of this process are reported.
创建时间：
2016-02-12
