Pyridyl-Directed Cp*Rh(III)-Catalyzed B(3)–H Acyloxylation of o‑Carborane
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https://figshare.com/articles/dataset/Pyridyl-Directed_Cp_Rh_III_-Catalyzed_B_3_H_Acyloxylation_of_i_o_i_Carborane/5422927
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An efficient pyridyl-directed Rh(III)-catalyzed o-carborane B(3)–H acyloxylation is reported. The B(3)–H bond is the most electron-deficient vertex on o-carborane whose functionalization is challenging. The combination of Cu(OH)2 and diverse carboxylic acids provides low cost and abundant acyloxyl sources which could lead to moderate to excellent yields.
创建时间：
2017-09-20
