Oxidative Route to Abnormal NHC Compounds from Singly Bonded [M–M] (M = Ru, Rh, Pd) Precursors
收藏Figshare2016-02-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Oxidative_Route_to_Abnormal_NHC_Compounds_from_Singly_Bonded_M_M_M_Ru_Rh_Pd_Precursors/2100064
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资源简介：
A new base-free entry to metal–aNHC compounds from metal–metal bonded bimetallic precursors and imidazolium salts is reported. Regioselective metalation proceeds via C–I oxidative addition of an annulated imidazo[1,2-a][1,8]naphthyridine system to [RuI–RuI], [RhII–RhII], and [PdI–PdI] single bonds, affording C5-bound (abnormal) RuII–, RhIII–, and PdII–NHC compounds, respectively, at room temperature and in high yields.
创建时间：
2016-02-12
