Synthesis of a Highly Functionalized Core of Verrillin
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https://figshare.com/articles/dataset/Synthesis_of_a_Highly_Functionalized_Core_of_Verrillin/2414197
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An efficient stereoselective synthesis of furanoverrillin (5), a highly functionalized core of verrillin (1), is reported. The synthetic strategy is based on constructing bicyclic lactone 17 prior to the 10-membered ring macrocyclization. The effect of the C4 methyl group on the furan reactivity is also discussed.
创建时间:
2016-02-19



