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Catalytic Enantioselective Conia-Ene Reaction

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Catalytic_Enantioselective_Conia_Ene_Reaction/3251605
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资源简介:
An enantioselective intramolecular Conia-ene reaction of β-dicarbonyl compounds and alkynes to afford methylene cyclopentanes is described. The reaction employs a DTBMSegphos-Pd(II)/Yb(III) dual catalyst system that allows for the asymmetric synthesis of all-carbon quaternary centers and generates a product containing an alkene that can be further manipulated.
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2016-05-05
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