ELECTRON-CATALYZED RADICAL PERFLUOROALKYLATION OF ORGANIC SULFIDES. THE SERENDIPITOUS USE OF TMEDA/I2 COMPLEX AS RADICAL INITIATOR
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资源简介：
Radical initiation for the perfluoroalkylation reaction of sulfides has been performed using the complex [(TMEDA) I.I3] and
visible light. This methodology bypasses the use of metal(organo)catalysts where the complex [(TMEDA) I.I3] acts as a good
electron donor / reductant radical initiating agent. Biologically-relevant sulfides are easily substituted with RF moieties
employing a mild and environmentally benign radical strategy starting from readily-available RFI.
创建时间：
2020-05-24
