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Calorimetric data of liquid Ag-Mg-Ti alloys

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DataCite Commons2025-08-29 更新2026-05-04 收录
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https://repod.icm.edu.pl/citation?persistentId=doi:10.18150/YWRKBW
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TXT files with column headers Index Time (h) Furnace Temperature (°C) Sample Temperature (°C) HeatFlow (µV). Calisto software version 1.39 (Setaram Instrumentation - KEP Technologies, Caluire, France) was used to measure thermal effects.The calorimetric data for five separate experimental series, with constant ratios of xAg/xMg = 9/1, 7/3, 1/1, and 3/7, and xAg/xTi = 19/1.Tab_2_Series_A.txt: 9/1 (xAg/xMg = 9/1);Tab_2_Series_A_prim.txt: 9/1 (xAg/xMg = 9/1);Tab_2_Series_B: 7/3 (xAg/xMg =7/3);Tab_2_Series_C: 1/1 (xAg/xMg =1/1);Tab_2_Series_D: 3/7 (xAg/xMg =3/7);Tab_3_Series_E: 19/1 (xAg/xTi = 19/1.).The measurements were performed using the drop calorimetry method at temperatures of 1294 K and 1297 K for the liquid solutions with the following constant mole fraction ratio: xAg/xMg = 9/1, 7/3, 1/1, 3/7 [(Ag0.9Mg0.1)1−xTix, (Ag0.7Mg0.3)1−xTix, (Ag0.5Mg0.5)1−xTix, (Ag0.3Mg0.7)1−xTix)], and xAg/xTi = 19/1 [(Ag0.95Ti0.05)1−xMgx].The experimental studies of liquid Ag-Mg-Ti alloys can be used in the future to optimize thermodynamic properties and phase diagram calculations. The results of drop calorimetric measurements at 1294 K and 1297 K for liquid Ag-Mg-Ti alloys indicate that the liquid solutions exhibit negative deviations from ideal behavior. The minimum integral molar enthalpy value was -13.444 kJ/mol for alloy Ag0.95Ti0.05 and xMg = 0.4182.
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2025-08-28
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