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A New Class of Near-Infrared Electrochromic Oxamide-Based Dinuclear Ruthenium Complexes

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/A_New_Class_of_Near_Infrared_Electrochromic_Oxamide_Based_Dinuclear_Ruthenium_Complexes/3314626
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We report the synthesis of a new class of symmetric and unsymmetric oxamide-based dinuclear ruthenium complexes. These complexes were characterized by NMR, ESI-MS, and electrochemical methods. Spectroelectrochemical analysis of the complexes showed broad absorptions in the NIR region for the mixed-valence state of the complexes. The introduction of a chiral group into the bridging ligand produced an optically active complex that was studied using circular dichroism.
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2016-05-06
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