Formation of a Double-Bicapped Hexatin Phosphate Cage by a De-arylation Reaction. Synthesis and Structure of [(PhSn)6(μ-OH)2(μ3-O)2(μ-OEt)4{(ArO)PO3}4] (Ar = 2,6-i-Pr2C6H3)
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https://figshare.com/articles/dataset/Formation_of_a_Double-Bicapped_Hexatin_Phosphate_Cage_by_a_De-arylation_Reaction_Synthesis_and_Structure_of_PhSn_sub_6_sub_-OH_sub_2_sub_sub_3_sub_-O_sub_2_sub_-OEt_sub_4_sub_ArO_PO_sub_3_sub_sub_4_sub_Ar_2_6-_i_i-_i_Pr_sub_2_sub_C_sub_6_su/12065724
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资源简介：
The reaction of bis(triphenyl)tin oxide, (Ph3Sn)2O, with 2,6-diisopropylphenylphosphate, (ArO)PO3H2 (Ar = 2,6-i-Pr2-C6H3), leads to the formation of a novel double-bicapped hexanuclear monoorganooxotin cage, [(PhSn)6(μ-OH)2(μ3-O)2(μ-OEt)4{(ArO)PO3}4]. This reaction proceeds by a de-arylation reaction involving the cleavage of Sn−C bonds.
创建时间：
2007-08-27
