Total Synthesis of (+)-Iresin
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https://figshare.com/articles/dataset/Total_Synthesis_of_Iresin/2166355
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资源简介：
The
first asymmetric total synthesis of (+)-iresin (4), an
historically important ent-Drimane sesquiterpene
lactone, was realized from aldehyde 3 via cyclic orthoester 6 in 5 steps. Notable transformations in this synthesis include
a tandem trifluoroperacetic acid (TFPAA)-mediated Baeyer–Villiger
oxidation–olefin epoxidation–epoxy ester cyclization,
regioselective Burgess dehydration, and regioselective Fétizon
oxidative lactonization.
创建时间：
2016-02-13
