Stereoselective Syntheses of Four Diastereomers of 3,9,12-Trihydroxycalamenene via a Benzobicyclo[3.3.1] Intermediate
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https://figshare.com/articles/dataset/Stereoselective_Syntheses_of_Four_Diastereomers_of_3_9_12_Trihydroxycalamenene_via_a_Benzobicyclo_3_3_1_Intermediate/2759578
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资源简介:
The highly stereoselective syntheses of four diastereomers of natural 3,9,12-trihydroxycalamenene are described. The syntheses highlight the utility of an unusual framework of benzobicyclo[3.3.1] lactones, which were accomplished via an intramolecular Friedel−Crafts-type Michael addition of α,β-unsaturated lactones.
创建时间:
2016-02-24



