On the [3 + 2] Annulation of Cyclic Allylsilanes with <i>N</i>-Phenyltriazolinedione: An Enantio- and Diastereoselective Synthesis of <i>cis</i>-1,3-Diaminocyclitols
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Improved conditions were found to trigger [3 + 2] annulation of cyclic allylsilanes with N-phenyltriazolinedione (PTAD); the products from this reaction were readily tailored into cis-1,3-diaminocyclitols in highly enantioenriched form with full stereochemical control of up to four contiguous stereogenic centers.
创建时间：
2010-07-02
