Enantioselective Total Synthesis of (+)-Salvileucalin B
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https://figshare.com/articles/dataset/Enantioselective_Total_Synthesis_of_Salvileucalin_B/2695567
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An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is reported. Key findings include a copper-catalyzed arene cyclopropanation reaction to provide the unusual norcaradiene core and a reversible retro-Claisen rearrangement of a highly functionalized norcaradiene intermediate.
创建时间:
2016-02-23



