Synthesis, Crystal Structure, and Luminescent Property of One 3D Porous Metal-Organic Framework With dmc Topology
收藏Taylor & Francis Group2016-01-20 更新2026-04-16 收录
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https://tandf.figshare.com/articles/dataset/Synthesis_Crystal_Structure_and_Luminescent_Property_of_One_3D_Porous_Metal_Organic_Framework_With_dmc_Topology/1568677/3
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资源简介：
One new 3D porous metal-organic framework {[Zn(ox)<sub>0.5</sub>(trz)]·0.25H<sub>2</sub>O}<sub><i>n</i></sub> (<b>1</b>) [trz = 1,2,4-triazole, ox = oxalate] has been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray crystallography, and powder X-ray diffraction (PXRD) analysis. The most remarkable structural feature of <b>1</b> is that the assembly of the Zn–trz 2D layers and the ox molecule pillars result in the formation of 3D pillared-layer dmc framework showing porous and helical character. In addition, thermal stability and the luminescent property of the complex have been investigated.
创建时间：
2015-10-17
