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Synthetic-Method-Dependent Magnetic Relaxation in a Cobalt(II) Phosphonate Chain Compound

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https://figshare.com/articles/dataset/Synthetic_Method_Dependent_Magnetic_Relaxation_in_a_Cobalt_II_Phosphonate_Chain_Compound/2230648
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资源简介:
A polar cobalt­(II) phosphonate Co­(bamdpH2)­(H2O) (1) [bamdpH4 = (benzylazanediyl)­bis­(methylene)­diphosphonic acid] is reported. It shows a linear chain structure. The neighboring chains are connected by moderately strong hydrogen bonds forming a supramolecular layer. The interlayer spaces are filled with the organic groups of the phosphonate ligands. Compound 1 displays the coexistence of single-chain magnet behavior and canted antiferromagnetism below 2.8 K. Moreover, the magnetic dynamics is strongly dependent on the synthetic methods, a phenomenon that has not been documented before.
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2014-12-01
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