Synthetic-Method-Dependent Magnetic Relaxation in a Cobalt(II) Phosphonate Chain Compound
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https://figshare.com/articles/dataset/Synthetic_Method_Dependent_Magnetic_Relaxation_in_a_Cobalt_II_Phosphonate_Chain_Compound/2230648
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资源简介:
A polar
cobalt(II) phosphonate Co(bamdpH2)(H2O) (1) [bamdpH4 = (benzylazanediyl)bis(methylene)diphosphonic
acid] is reported. It shows a linear chain structure. The neighboring
chains are connected by moderately strong hydrogen bonds forming a
supramolecular layer. The interlayer spaces are filled with the organic
groups of the phosphonate ligands. Compound 1 displays
the coexistence of single-chain magnet behavior and canted antiferromagnetism
below 2.8 K. Moreover, the magnetic dynamics is strongly dependent
on the synthetic methods, a phenomenon that has not been documented
before.
创建时间:
2014-12-01



