Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Investigating_the_Dearomative_Rearrangement_of_Biaryl_Phosphine_Ligated_Pd_II_Complexes/2464129
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A series of monoligated L·PdII(Ar)X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented PdII-mediated insertion of an aryl group into an unactivated arene.
创建时间：
2016-02-20
