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Rh-Catalyzed Cyclization of Diynes and Enynes Initiated by Carbonyl-Directed Activation of Aromatic and Vinylic C−H Bonds

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Rh_Catalyzed_Cyclization_of_Diynes_and_Enynes_Initiated_by_Carbonyl_Directed_Activation_of_Aromatic_and_Vinylic_C_H_Bonds/2993173
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The Rh-catalyzed hydroarylative and hydrovinylative cyclization of diynes with aryl ketones or enones gave monocyclic 1,3-dienes. Enynes also underwent the same reaction and chiral products were obtained with high ee using a chiral Rh catalyst. Carbonyl-directed activation of aromatic and vinylic C−H bonds is likely the initial step in the present transformation.
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2016-06-03
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