Catalytic Asymmetric Synthesis of Pyrroloindolines via a Rhodium(II)-Catalyzed Annulation of Indoles
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https://figshare.com/articles/dataset/Catalytic_Asymmetric_Synthesis_of_Pyrroloindolines_via_a_Rhodium_II_Catalyzed_Annulation_of_Indoles/2416948
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资源简介：
Herein
we report the synthesis of pyrroloindolines via a
catalytic enantioselective formal [3+2] cycloaddition of C(3)-substituted
indoles. This methodology utilizes 4-aryl-1-sulfonyl-1,2,3-triazoles
as carbenoid precursors and the rhodium(II)-tetracarboxylate catalyst
Rh2(S-PTAD)4. A variety of
aryl-substituted pyrroloindolines were prepared in good yields
and with high levels of enantioinduction.
创建时间：
2016-02-19
