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Synthesis and Structural Revision of (±)-Laurentristich-4-ol

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https://figshare.com/articles/dataset/Synthesis_and_Structural_Revision_of_Laurentristich_4_ol/2964745
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The structure of tetracyclic natural sesquiterpene laurentristich-4-ol was revised based on its synthetic studies. The proposed and the revised structures of laurentristich-4-ol were both synthesized with SmI2-mediated ketyl radical cyclization as the key step to construct the spirocyclic ether skeleton.
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2008-01-04
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