The Stereoselective Formation of Bicyclic Enamines with Bridgehead Unsaturation via Tandem C−H Bond Activation/Alkenylation/Electrocyclization
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https://figshare.com/articles/dataset/The_Stereoselective_Formation_of_Bicyclic_Enamines_with_Bridgehead_Unsaturation_via_Tandem_C_H_Bond_Activation_Alkenylation_Electrocyclization/2955127
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资源简介：
Bridgehead bicyclic unsaturated enamines were prepared by a tandem rhodium-catalyzed C−H bond activation/alkenylation/electrocyclization of alkyne-tethered unsaturated imines. These strained bicyclic enamines exhibit unique reactivity: for example, they give N-alkylated products upon treatment with alkylating reagents and undergo double-bond isomerization to alleviate ring strain upon reduction.
创建时间：
2016-06-03
