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Broad Scope Aminocyclization of Enynes with Cationic JohnPhos–Gold(I) Complex as the Catalyst

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Broad_Scope_Aminocyclization_of_Enynes_with_Cationic_JohnPhos_Gold_I_Complex_as_the_Catalyst/2113339
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A practical aminocyclization of 1,6-enynes with a wide variety of substituted anilines, including N-alkyl anilines, has been achived by using cationic [JohnPhosAu­(MeCN)]­SbF6 as a general purpose catalyst. The resulting adducts can be easily converted into polycyclic compounds by palladium- and gold-catalyzed reactions.
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2016-02-03
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