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Radical trans-Hydroboration of Substituted 1,3-Diynes with an N‑Heterocyclic Carbene Borane

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Figshare2021-01-22 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Radical_i_trans_i_-Hydroboration_of_Substituted_1_3-Diynes_with_an_i_N_i_Heterocyclic_Carbene_Borane/13628092
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资源简介:
Monohydroboration of substituted 1,3-diynes with an N-heterocyclic carbene borane (NHC–borane) occurs under radical conditions using an azo initiator, such as ACCN and AIBN, and a thiol as a polarity-reversal catalyst. The reaction is highly regio- and stereoselective and provides stable NHC-(E)-alkynylalkenylboranes.
创建时间:
2021-01-22
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