Biogenic Emissions and Aerosol Response on the North Slope (BEAR-oNS) datasets for Utqiagvik, Alaska in the summer of 2023

Climate in the Arctic is changing at a rapid pace. When vegetation reacts to these changes, chemicals called biogenic volatile organic compounds (BVOCs) can be released into the atmosphere in new ways. This project seeks to investigate how climate change affects the quantity and type of BVOCs released into the atmosphere on the North Slope of Alaska (NSA). In addition, we are interested in the chemical reactions these BVOCs undergo in the Arctic atmosphere. Project goals will be accomplished through field work on the NSA, and collection and laboratory analysis of atmospheric samples. Specifically, the project intends to measure the concentration of BVOCs and their secondary organic aerosol products during North Slope of Alaska field campaigns. In addition to BVOCs and organic acids, the measurements include additional baseline measurements of other volatile organic compounds (VOC) and aerosol components. We are reporting inorganic ions, alkanes, and polycyclic aromatic hydrocarbons (PAHs) for aerosol composition and select aromatic and oxidized VOCs. The time period for these detailed measurements is Jun - Aug 2023 for Utqiagvik, Alaska (AK).
VOC measurements were made by proton transfer reaction mass spectrometry. The proton transfer reaction mass spectrometer (PTR-MS) was operated with Hydronium (H3O+) ion at the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) site in Utqiagvik, AK from 170623 to 130823. Total suspended particulate matter samples were collected on quartz fiber filters at a roughly weekly schedule. These filters were then used for offline analysis. Offline measurement of cations and anions was conducted using ion chromatography. Offline measurement of alkanes and PAH was conducted using thermal desorption gas chromatography - mass spectrometry.