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Undulating Layers in a New Rhodate Network: Structure of Bi1.4CuORh5O10

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Undulating_Layers_in_a_New_Rhodate_Network_Structure_of_Bi_sub_1_4_sub_CuORh_sub_5_sub_O_sub_10_sub_/2601475
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A new rhodate, Bi1.4CuRh5O11, with an hitherto unknown channel structure containing undulating layers of RhO6 octahedra sharing corners and edges has been discovered and its structure refined from single crystal X-ray diffraction data. The channels contain Bi3+, Cu2+, and some O strongly bound to Cu. The Cu coordination is distorted square planar. Mixed Rh3+/Rh4+ valency leads to significant electrical conductivity.
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2016-02-22
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