Regioselective Thiolation of Arenes and Heteroarenes: C–H Functionalization Strategy for C–S Bond Formation
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https://figshare.com/articles/dataset/Regioselective_Thiolation_of_Arenes_and_Heteroarenes_C_H_Functionalization_Strategy_for_C_S_Bond_Formation/2244022
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资源简介：
A facile transition-metal-free
oxidative cross-dehydrogenative
coupling reaction involving selective formation of a C–S bond
leading to the synthesis of arylthiobenzoxazoles, heteroarylthiobenzoxazoles,
and arylthiobenzothiazoles has been described. This highly regioselective
C–H functionalization reaction with electron-rich aromatic
systems including heteroaromatics is achieved by reversing the reactivity
of sulfur in the presence of a suitable oxidant and strong acid.
创建时间：
2016-02-16
