Efficient Diels–Alder Addition of Cyclopentadiene to Lithium Ion Encapsulated [60]Fullerene
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Much higher reactivity of [Li+@C60]PF6– for Diels–Alder cycloaddition toward cyclopentadiene (CpH), in comparison with that of empty C60, was observed. The synthetic method, electrochemical and light absorption properties, and X-ray crystal structure of the product [Li+@C60(CpH)]PF6– are discussed.
创建时间:
2016-02-18



