Three-Electron Nickel(I)/Nickel(0) Half-Bond
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https://figshare.com/articles/dataset/Three-Electron_Nickel_I_Nickel_0_Half-Bond/21256140
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资源简介：
An (N-heterocyclic carbene)nickel(I) cation precursor
reacts with
the corresponding nickel(0) complex to form a dinickel(I,0) monocation.
The Ni···Ni distance in this cation is 0.93 Å
shorter than in the analogous dinickel(0) complex. Although the solid-state
structure shows equivalent Ni centers, density functional theory calculations
indicate significant electronic localization. Reactions with CO and
NO form mononuclear carbonyl and nitrosyl complexes. Oxidative addition
of an aryl bromide results in C-arylation of the
carbene ligands.
创建时间：
2022-09-30
